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Krogmann's salt : ウィキペディア英語版 | Krogmann's salt
Krogmann's salt is a mixed-valence square planar coordination complex of platinum and cyanide bonded through linear platinum metal chains, sometimes described as molecular wires. Although the term Krogmann’s salt most commonly refers to a platinum metal complex of the formula K2() where X is usually bromine (or sometimes chlorine), a number of non-stoichiometric metal salts containing the anionic complex ()2− can also be characterized under the blanket term “Krogmann’s salts.” Modeled as an infinite one-dimensional molecular chain of platinum atoms, the high anisotropy and restricted dimensionality of Krogmann’s salt and related compounds are becoming increasingly attractive properties for many facets of nanotechnology. ==History==
Krogmann’s salt was first synthesized by Dr. Klaus Krogmann in the late 1960s at the University of Stuttgart in Germany. Dr. Krogmann published the original journal article documenting the synthesis and characterization of the salt in 1969.〔 〕
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